Product ID:1613 SEMI-FLAT BLACK KRYLON INT/EXT ENAMEL AEROSOL
MSDS Date:04/10/1989
FSC:NIIN:Submitter:D RV
Status Code:A
MSDS Number: CKNYX

KRYLON, THE SHERWIN-WILLIAMS CO., SPECIALITY DIV.

6830 COCHRAN ROAD
SOLON, OH 44139-3908
US

Emergency Phone: 216-292-7400

Info Phone: 216-292-7400

Cage: EO276

WALTER RB AFFIL OF SAX ARTS AND CRAFTS INC

51710 NEW BERLIN, WI 53151-0710 US

Telephone: 414-784-6880

Cage: 0RKV4

ACETONE (SARA 313) (CERCLA)

CAS: 67-64-1

RTECS: AL3150000

OSHA PEL 1000 PPM

ACGIH TLV: 750PPM/1000STEL;9495

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

N-BUTYL ALCOHOL (SARA 313) (CERCLA)

CAS: 71-36-3

RTECS: EO1400000

OSHA PEL 100 PPM

ACGIH TLV: S, C 50 PPM; 9495

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

PROPANE

CAS: 74-98-6

RTECS: TX2275000

OSHA PEL 1000 PPM

ACGIH TLV: ASPHYXIANT; 9495

METHYL ETHYL KETONE (2-BUTANONE) (MEK) (SARA 313) (CERCLA)

CAS: 78-93-3

RTECS: EL6475000

OSHA PEL 200 PPM

ACGIH TLV: 200 PPM/300STEL;9495

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

METHYL ISOBUTYL KETONE (HEXONE) (SARA 313) (CERCLA)

CAS: 108-10-1

RTECS: SA9275000

OSHA PEL 100 PPM

ACGIH TLV: 50 PPM/75 STEL; 9495

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

PROPYLENEGLYCOL MONOMETHYL ETHER ACETATE; 2-PROPANOL,

CAS: 108-65-6

RTECS: AI8295000

OSHA PEL NOT ESTABLISHED.

ACGIH TLV: NOT ESTABLISHED.

TOLUENE (SARA 313) (CERCLA)

CAS: 108-88-3

RTECS: XS5250000

OSHA PEL 200 PPM; Z-2

ACGIH TLV: S, 50 PPM; 9495

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

XYLENES (O-,M-,P- ISOMERS) (SARA 313) (CERCLA)

CAS: 1330-20-7

RTECS: ZE2100000

OSHA PEL 100 PPM

ACGIH TLV: 100 PPM/150STEL;9495

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:CNS DEPRESS.REPORTS HAVE ASSOC
REP/PROL OCCUPAT OVEREXPO TO SOLVTS W/PERM BRAIN/CNS
DMG.INTENTIONAL MISUSE BY DELIBERATELY CONCEN/INHAL CONTENTS MAY
LEAD TO ADDICTION/HARMFUL/FATAL.LIVER/KIDNEY DMG.RE PRODUCTIVE
DISORDERS BASED ON ANIMAL DATA.SKIN ABSORPTION:NO HAZ
KNOWN.INGEST:NOT EXPECTED TO BE HARMFUL UNDER (SUPPLEM)
Explanation of Carcinogenicity:PER MSDS:THIS MATL HAS NOT BEEN LISTED
BY NTP/IARC/OSHA AS CARCINOGEN.
Effects of
Overexposure:HEADACHE,DIZZINESS,NAUSEA,VOMITING,UNSONC,ASPHYXIATION
. CYANOSIS,RESP DISTRESS,DROWSINESS.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:INGEST:DILUTE BY DRINKING LG QUANT OF WATER.IMMED CONTACT
POIS CNTNRL CNTR/HOSPITAL EMERG RM FOR OTHER ADDN TREAT
DIR.INHAL:REMOVE TO FRESH AIR.NOT BREATH GIVE ART RESP PREFER
MOUTH-TO-MOUTH.SKIN:FLUS H W/PLENTY OF WATER FOR @LEASAST
15MINS;EYELIDS HELD APART DURING IRRIGATION TO INSURE WATER CONTACT
W/ENITRE SURFACE OF EYES/LIDS.CALL PHYSICIAN.

Extinguishing Media:USE DRY CHEMICAL, FOAM OR COW. WATER MAY BE
INEFFECTIVE BUT SHOULD BE USED TO KEEP FIRE-EXPO CNTNRS COOL.
Fire Fighting Procedures:NONE SPECIFIED BY MANUFACTURER; HMIS:USE
APPROPRIATE PPE AS CONDITIONS WARRANT.
Unusual Fire/Explosion Hazard:EXTREM FLAMM.HI TEMPS MAY CAUSE
BURSTING.VAP MAY IGN EXPLO.SPRAY MIST/VAP EVAPORA FRM DEPO FILM
HEAVIER THAN AIR;SETTLE IN LOW PLACES/TRAVEL TO IGN SOURCE;FLSBK

Spill Release Procedures:ELIMINATE ALL IGNITION SOURCES.SOAK UP
W/ABSORBENT MATL & REMOVE TO CHEMICAL DISPOSAL AREA.PREVENT ENTRY
INTO NATURAL BODIES OF WATER.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:AVOID BREATH VAP/MIST.USE W/ADQUA
VENTI.AVOID EYE/SKIN CONTACT.AVOID HEAT.KEEP CNTNR <120F.DO NOT
PUNCTURE CNTNR-CONTENTS UNDER PRESS WILL DISCHARGE.
Other Precautions:DO NOT SMOKE.HNDL IAW GOOD INDUSTRIAL HYGIENE/SAFETY
PRACTICES WHICH INCLUDE AVOIDING UNNECESSARY EXPO/REMOVEAL OF MATL
FROM EYE/SKIN/CLOTH.INSTRUCT YOUR WORKERS TO HANDLE PRODUCT
PROPERLY.BEFORE USIN G/HNDLG READ/UNDERSTAND MSDS.

Respiratory Protection:WHERE AIR CONTAMINANTS CAN EXCEED ACCEPTABLE
CRITERIA USE NIOSH/MSHA APPROVED RESP PROT EQUIPMENT.RESP SHOULD BE
SELECTED BASED ON FORM/CONCEN OF CONTAMIN IN AIR IAW OSHA 29CFR
1910.134 OR OTHER APPLI CABLE STD/GUIDELINES.
Ventilation:LOC EXHAUS VENTI,ENCLSD SYS DESIGN,PROCESS ISOLATION/REMOTE
CNTRL COMBINE W/APPROP USE OF PPE/PRUDENT WORK PRACTICES.
Protective Gloves:IMPERVIOUS GLOVES.
Eye Protection:GOGGLES IF CONTACT IS LIKELY.
Other Protective Equipment:CONSULT EXPERTS OF YOUR CHOICE TO DETERMINE
WHETHER OR NOT YOUR ENGINEERING CONTROLS PROGRAMS ARE ADEQUATE.
Work Hygienic Practices:WASH THOROUGHLY AFT HNDLG.
Supplemental Safety and Health
PRESSURE IN CAN @70F:APPROX 60PSIG. HEALTH HA:NORMAL CONDITONS OF
USE.INGEST:BURNS/IRRIT MUC MEMB/ESOPHAGUS/GI
TRACT.INHAL:HARMFUL.LIQ/VAP IRRIT NOSE/THROAT/LUNGS.CNS
DEPRESS.SKIN/EYE:IRRIT. DISPO:XYL
ENE;2-PROPANOL,1-METHOXY-,ACETATE.

HCC:V3
Vapor Pres:SEE CAN
Vapor Density:>AIR
Spec Gravity:LITER THAN H2O
Evaporation Rate & Reference:FASTER THAN BUTYL ACETATE
Solubility in Water:SLIGHT
Percent Volatiles by Volume:81-89

Stability Indicator/Materials to Avoid:YES
NONE SPECIFIED BY MANUFACTURER.
Stability Condition to Avoid:DO NOT PLACE CNTNR ON RADIATOR/STOVE/IN
DIRECT SUNLIGHT/NEAR OTHER HEAT SOURCES.AVOID OPN
FLAME/SPARKS/PILOT LIGHTS.
Hazardous Decomposition Products:OXIDES OF CARBON.

Waste Disposal Methods:DO NOT BURN CNTNR.DISPOSE IAW
LOC/STATE/PROVIN/FED REQMTS.EMPTY CNTNR MAY CONTAIN EXPLO VAP.DO
NOT CUT/PUNCTURE/WELD ON/NEARBY.CONTAINS CHEM SUBJ TO REPROTING
REQMTS SEC 313 TITLE III SARA/4CFR PART37 2:ACETONE;N-BUTYL
ALCOHOL;MEK;MIK;TOLUENE;(SUPPLE)

SARA Title III Information:THIS PRODUCT CONTAINS THE FOLLOWING TOXIC
CHEMICALS SUBJECT TO THE REPORTING REQUIREMENTS OF SECTION 313:
ACETONE, N-BUTYL ALCOHOL, METHYL ETHYL KETONE, METHYL ISOBYTYL
KETONE, 2-PROPANOL 1-METHOXY AC ETATE, TOLUENE, XYLENE MIXED
ISOMERS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.